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A packaged aluminum–graphite battery is estimated to deliver an energy density of ≈150 Wh kg−1 at a power density of ≈1200 W kg−1, which is ≈50% higher than most commercial lithium ion batteries.
Lithium ion batteries based on cation intercalation have been powering the increasingly mobile society for decades.[1] In a conventional lithium ion battery, the intercalation of lithium ions in both cathode (i.e., LiCoO2, LiFePO4) and anode (i.e., graphite, silicon) materials have been thoroughly studied, while the utilization of the anions in the electrolyte has drawn much less attention.[2] In fact, the phenomenon of anion intercalate into graphite by chemical or electrochemical means was discovered and proposed as a possible positive electrode for batteries by Rüdorff and Hofmann in 1938.[3] However, the anion intercalation was achieved by using high concentration acid solution as electrolyte, this brought serious safety issue that hindered its application.[4] In the 1990s, soon after the commercial application of lithium ion battery, Carlin et al. reported dual graphite intercalating molten electrolyte batteries that realized the application of anion intercalated graphite as positive electrode in batteries by using room temperature ionic liquids as electrolyte.[5] In the following decades, continuous progresses have been made in anion intercalated graphite based dual carbon batteries, such as investigation of anion intercalation in non-aqueous electrolyte, in situ characterization of the staged anion intercalation process, and systematic study of the intercalation of different anions into graphite.[6]